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Review Article: Al-Afif                                                                         24


            D              to    rapid    industrialization,      biofuels.
            Introduction                                          sugarcane as a feedstock for the manufacture of
                     ue
                     urbanization,  and  population  growth,
                     the  demand  for  energy  and  its
            resources is increasing annually. It is projected
            that global energy consumption will reach 812
            quadrillion  KJ  in  2035, meanwhile,  fossil fuels
            are still the dominant energy source. The use of
            petroleum  and  other  liquid  fossil  fuels
            worldwide was 85.7 million barrels/day in 2008
            and  is  expected  to  increase  to  112.2  million
                                (1)
            barrels/day in 2035  . It is expected that we will
                                                        (2)
            deplete the entire global oil reserve by 2050  .            Fig. 1 Conversion of biomass to bioenergy
            Approximately  86%  of  global  CO2  emission  is
            associated  with  the  use  of  fossil  fuels  with  2   In the future, efficiency can be further improved
                              -1
            billion  tons  year   discharged  by  coal-fired      through  the  development  of  superior  crop
            power plants as prevalent around the globe  (3,4) .   varieties,   improved    crop    management
            Due to concerns over rising fuel prices, declining    techniques,  and  advancements  in  ethanol
                                                                                       (8)
                                                                  production processes  . The only other biofuel
            reserves  of  fossil  fuels,  and  environmental
            issues such as pollution and global warming, a        made  on  an  industrial  basis  is  biodiesel
                                                                  produced  from  oily  plants  and  seeds  and
            novel,  sustainable  approach  to  energy
                                                                  commonly used in Europe and Asia   (14) . There is
            production  is  urgently  needed.  Biomass  and
            fuels  derived  from  its  processing  are  one  of   a number of environmental and socioeconomic
                                                                  concerns  around  the  first  generation  biofuels
            promising  alternatives  to  conventional  fossil
                  (5)
            fuels  . Sustainability, feedstock diversity, and     future  perspective  such  as  land  use,  food
                                                                                              (15)
            low to no emissions of gasses such as soot, SO2,      competitivness, and lifecycle   .  Moreover, the
                                                                  growth  is  dictated  by  biomass  prices  on  the
            or  NOx  make  biomass  a  promising  energy
                                                                  market. Some of these challenges are banished
            source.  However,  treatment  is  needed  for
            biomass  to  be  converted  into  biofuels  and       through  newer  generation  fuels.  Second
                                                                  generation biofuels utilize the range of different
            chemicals that have ready use due to its high
                                                                  feedstocks  such  as  non-edible  lignocelulosic
            moisture and oxygen content and consequently
            lower  energy-density compared  to  fossil fuels      biomass, different residues and waste products
            (6,7) .  According  to  Faaij  (2006)  research,  bio-  such  as  bio-waste  and  municipal  solid  waste
                                                                  (14,16) .
            energy could meet current global energy needs
                                                      -1 (8)
            with  a  potential  of  over  1000  EJ  year    .     Thermochemical conversion
            Additionally, biofuels are carbon neutral as the      The  most  well-known  method  of  converting
            CO2 released by their combustion is consumed          biogenic waste is thermochemical conversion,
            again  for  the  growth  of  other  biomass  via      which  also  includes  pyrolysis,  gasification,
                            (1)
            photosynthesis  . Fig. 1 shows the conversion         liquefaction, hydropyrolysis, and reforming  (17–
            routes of biomass to bioenergy. Biogas, ethanol       21) .  The  biomass  is  transformed  into
            and biodiesel are examples of first-generation        hydrocarbons  and  synthesis  gas    through
            biofuels that are directly tied to biomass that is    gasification, whereas pyrolysis and liquefaction
            frequently edible  (9–13) . To make first-generation   directly  transform  the  biomass  at  high
            bioethanol, only a few distinct feedstocks are        temperatures into bio-oils, gases, and char.

            actually employed, namely sugarcane or corn.
            Brazil  is  one  of  the  top  countries  using

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